PUBLICATION

Research Papers  (研究論文)

2022

28. Theoretical Study on C-H Borylation Catalyzed by PNN Iron Pincer Complex, Kazuki Kanemitsu, Hidetaka Yuge, Masahiro Kamitani, manuscript in preparation.

27. Group 10 Transition Metal Complexes Supported by a Quinoline-based SiNN Pincer Ligand, Takato Saito, Takumi Toriyabe, Hidetaka Yuge, Masahiro Kamitani,* manuscript in preparation.

26. Earth abundant 3d transition metals (Fe, Co, Ni) for non-directed C-H borylation, Masahiro Kamitani,* Wiley-VCH, accepted. (book chapter in Handbook of C-H functionalization: Ed. by D. Maiti)


2021

25. Chemically Robust and Readily Available Quinoline-based PNN Iron Complexes: Application in C-H Borylation of Arenes, Masahiro Kamitani,* Chemical Communications, 2021, 57, 13246-13258. (Feature Article, themed collection: Functionalization of unreactive C-H bonds)
DOI:10.1039/D1CC04877E


2020

24. Hemisphere and Distance-dependent Steric Analysis of PNN Iron Pincer Complexes using SambVca 2.1 and its Influence on Alkene Hydrosilylation, Masahiro Kamitani,* Kouta Yujiri, Hidetaka Yuge, Organometallics, 2020, 39, 3535-3539.
DOI:10.1021/acs.organomet.0c00512


2019

23. Development of Activator-free Iron Pincer Complexes for Alkene Hydrosilylation and Elucidation of its Activation Mechanism, Masahiro Kamitani,* Haruki Kusaka, Hidetaka Yuge, Chemistry Letters, 2019, 48, 1196-1198.
DOI: 10.1246/cl.190521

22. Iron-catalyzed Versatile and Efficient C(sp2)-H Borylation, Masahiro Kamitani,* Haruki Kusaka, Hidetaka Yuge, Chemistry Letters, 2019, 48, 898-901 (Open Access).
DOI: 10.1246/cl.190345

pub20

2018

21. Facile Entry to Iron Complexes Supported by Quinoline-based PNN Pincer Ligand, Masahiro Kamitani,* Haruki Kusaka, Takumi Toriyabe and Hidetaka Yuge, Bulletin of the Chemical Society of Japan, 2018, 91, 1429-1435.
DOI: 10.1246/bcsj.20180124

20. Dihydride Iron Complex Bearing a Silyl Tethered Cyclopentadienyl Ligand, Masahiro Kamitani,* Yoshinori Nishiguchi, Masumi Itazaki, Hiroshi Nakazawa,* Bulletin of the Chemical Society of Japan, 2018, 91, 588-594. (Selected Paper, Cover Art)
DOI: 10.1246/bcsj.20170403


2017

19. Polyhydrides of Sc, Zr and Hf and Their Proposed Formation, Takashi Kurogi, Masahiro Kamitani, Patrick J. Carroll and Daniel J. Mindiola*, Israel Journal of Chemistry, 2017, 57, 999-1009.
DOI: 10.1002/ijch.201700062

18. Room Temperature Ring-Opening of Quinoline, Isoquinoline and Pyridine with Low-Valent Titanium, Seung-yeol Baek, Takashi Kurogi, Dahye Kang, Masahiro Kamitani, Seongyeon Kwon, Douglas P. Solowey, Chun-Hsing Chen, Maren Pink, Patrick J. Carroll, Daniel J. Mindiola,* and Mu-Hyun Baik,* Journal of the American Chemical Society, 2017, 139, 12804-12814.
DOI: 10.1021/jacs.7b07433

17. Reactivity Studies of a Zirconium Methylidene Complex. Group Transfer and Methylenation Reactions, Kurogi Takashi, Masahiro Kamitani, Brian C. Manor, Patrick J. Carroll, Daniel J. Mindiola,* Organometallics, 2017, 36, 74-79.
DOI: 10.1021/acs.organomet.6b00594

16. Direct C─H Functionalization of Methane by Homogeneous Catalysis, Masahiro Kamitani,* Journal of Synthetic Organic Chemistry, Japan, 2017, 75, 1290-1291.
DOI: 10.5059/yukigoseikyokaishi.75.1290


2016

15. Synthesis of Vinylphosphine and Unsymmetric Diphosphine: Iron-catalyzed Selective Hydrophosphination Reaction of Alkynes and Vinylphosphines with Secondary Phosphines, Masumi Itazaki,* Shinya Katsube, Masahiro Kamitani, Hiroshi Nakazawa,* Chemical Communications, 2016, 52, 3163-3166.
DOI: 10.1039/C5CC10185A


2015

14. Redox and Reactivity of Cyclo-P3 Complexes of Vanadium and the Origin of their 31P NMR Spectroscopic Chemical Shift, Balazs Pinter, Kyle T. Smith, Masahiro Kamitani, Eva M. Zolnhofer, Ba L. Tran, Skye Fortier, Maren Pink, Gang Wu, Brian C. Manor, Karsten Meyer,* Mu-Hyun Baik,* Daniel J. Mindiola,* Journal of the American Chemical Society2015, 137, 15247-15261.
DOI: 10.1021/jacs.5b10074

13. Phosphino-Alkylidene and -Alkylidyne Complexes of Titanium. Intermolecular C-H Bond Activation and Dehydrogenation Reactions, Masahiro Kamitani, Balázs Pintér, Keith Searles, Marco G. Crestani, Anne Hickey, Brian C. Manor, Patrick J. Carroll, Daniel J. Mindiola,* Journal of the American Chemical Society, 2015, 137, 11872-11875.
DOI: 10.1021/jacs.5b06973

12. beta-Hydrogen Abstraction Provides Facile Entry to Stable Titanium and Zirconium Ethylene Complexes, Masahiro Kamitani, Keith Searles, Chun-Hsing Chen, Patrick J. Carroll, Daniel J. Mindiola,* Organometallics, 2015, 34, 2558-2566.
DOI: 10.1021/om501226k


2014 and earlier

11. Mononuclear and Terminal Zirconium and Hafnium Methylidenes, Masahiro Kamitani, Balazs Pinter, Chun-Hsing Chen, Patrick J. Carroll and Daniel J. Mindiola,* Angewandte Chemie International Edition, 2014, 53, 10913-10915.
DOI: 10.1002/anie.201405042 (Selected as a Hot Paper and a Cover Art)

10. Effective Dehydrogenation of 2-Pyridylmethanol Derivatives Catalyzed by an Iron Complex, Masahiro Kamitani, Masaki Ito, Masumi Itazaki, Hiroshi Nakazawa,* Chemical Communications, 2014, 50, 7941-7944.
DOI: 10.1039/C4CC01498G

9. Synthesis of Fe-H/Si-H and Fe-H/Ge-H Bifunctional Complexes and Their Catalytic Hydrogenation Reaction toward Non-polar Unsaturated Organic Molecules, Masahiro Kamitani, Yoshinori Nishiguchi, Ryosuke Tada, Masumi Itazaki, Hiroshi Nakazawa,* Organometallics, 2014, 33, 1532-1535.
DOI: 10.1021/om5000562

8. Recent Researches on Hydrogen Generation Reaction Catalyzed by Group 8 Transition-Metal Complex, Masumi Itazaki,* Masahiro Kamitani, Bulletin Japan Society of Coordination Chemistry, 2013, 62, 23-26.
DOI: 10.4019/bjscc.62.23

7. Regioselective Double Hydrophosphination of Terminal Aryacetylenes Catalyzed by an Iron Complex, Masahiro Kamitani, Masumi Itazaki, Chihiro Tamiya, Hiroshi Nakazawa,* Journal of the American Chemical Society, 2012, 134, 11932-11935.
DOI: 10.1021/ja304818c

6. Catalytic Synthesis of Cyclic and Linear Germoxanes Mediated by Iron Complex, Masahiro Kamitani, Kozo Fukumoto, Ryosuke Tada, Masumi Itazaki, Hiroshi Nakazawa,* Organometallics, 2012, 31, 2957-2960.
DOI: 10.1021/om3001845

5. Selective Dehydrogenativesilylation-Hydrogenation Reaction of Divinyldisiloxane with Hydro- silane Catalyzed by an Iron Complex, Roman Naumov, Masumi Itazaki, Masahiro Kamitani, Hiroshi Nakazawa,* Journal of the American Chemical Society, 2012, 134, 804-807.
DOI: 10.1021/ja209436s

4. Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl) hydridoiron complexes as a catalyst precursor, Masumi Itazaki, Masahiro Kamitani, Hiroshi Nakazawa,* Chemical Communications, 2011, 47, 7854-7856.
DOI: 10.1039/C1CC12530C

3. Synthesis, Characterization, and Crystal Structure of Germyl(phosphine)iron Complexes, Cp(CO)Fe(PPh3)(GeR3) (R = Et, nBu, Ph), Prepared from Cp(CO)Fe (PPh3)(Me) and HGeR3, Masumi Itazaki, Masahiro Kamitani, Yasuhiro Hashimoto, Hiroshi Nakazawa,* Phosphorus, Sulfur, and Silicon and the Related Elements, 2010, 185, 1054-1060.
DOI:10.1080/10426501003773373

2. Syntheses and Ligand Exchange Reaction of Iron(IV) Complexes with Two Different Group 14 Element Ligands, Cp(CO)FeH(EEt3)(E’Et3) (E, E’ = Si, Ge, Sn), Masumi Itazaki, Masahiro Kamitani, Kensuke Ueda, Hiroshi Nakazawa,* Organometallics, 2009, 28, 3601-3603.
DOI: 10.1021/om900225x

1. Carbonyl(η5-cyclopentadienyl)(pyridine)(triethylstannyl)iron(II),Masumi Itazaki, Masahiro Kamitani, Hiroshi Nakazawa,* Acta Crystallographica Section E, 2008, 64, m1578.
DOI: 10.1107/S1600536808037781

PATENT (特許)

2. 神谷昌宏、「3座配位子を有する鉄錯体化合物及びその製造方法、並びに有機ボロン酸エステルの製造方法」

1. 中沢浩、神谷昌宏、他 「有機ケイ素化合物の製造方法」

MISCELLANEOUS(その他、新聞報道等、査読のない研究記事)

8. Replacing platinum catalysts with iron catalysts for silicone production, Masahiro Kamitani,* Open Access Government, 2021, 32 (Oct), 258-259. website, website

7. Improvements in chemical processes using iron catalysts, Masahiro Kamitani,* Open Access Government, 2021, 31 (July), 268-269. website, website

6. The Kamitani research group – Improving industrial reactions using iron, Open Access Government, website

5. 高機能な有機ケイ素材料の製造に適した鉄錯体触媒の開発に成功 ―空気中で安定な鉄触媒として東京化成工業から発売―(Press Release, Dec 14, 2020)

プレス発表:北里発表 NEDO発表 

関連紙面記事 (printed newspaper):
- 有機ケイ素材料 高機能化、安価提供へ(電波新聞, Dec 25, 2020)
- 有機ケイ素材料に適した鉄錯体触媒 NEDO など(化学工業日報, Dec 18, 2020)

主要なオンライン記事 (Online news):
- 毎日新聞 朝日新聞デジタル 新潟新聞 沖縄タイムス  北海道新聞  BIGLOBEニュース Infoseekニュース 日本の研究.com ZDNet Japan

4. PNN iron pincer complex:TCI product page, D5886

3. Focusing on the research work undertaken in the Kamitani Group (Oct 01, 2020) Website

2. 近畿化学協会有機金属部会 海外研究室レポート(ペンシルバニア大学、Mindiola教授研究室), 神谷昌宏, OMnews 2018, 3, 93-94. website

1. 2 つの 14 族配位子を有する 4 価鉄錯体における配位子置換反応, Bulletin of Japan Society of Coordination Chemistry, 2008, 53, 62-64.